Systematic study of thiazole incorporated NLO gradient bridge chromophores

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Systematic study of thiazole incorporated NLO gradient bridge chromophores

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dc.contributor.author Casmier, Daniel Michael en_US
dc.date.accessioned 2009-10-06T21:47:26Z
dc.date.available 2009-10-06T21:47:26Z
dc.date.issued 2004 en_US
dc.identifier.other b53178737 en_US
dc.identifier.other 58802937 en_US
dc.identifier.other Thesis 54030 en_US
dc.identifier.uri http://hdl.handle.net/1773/8487
dc.description Thesis (Ph. D.)--University of Washington, 2004 en_US
dc.description.abstract In an exploration of improving the intrinsic first order hyperpolarizability of organic NLO chromophores, sets of novel chromophores were synthesized. These compounds were designed according to a novel gradient bridge concept. Among these novel compounds, the first experimental example of a thiazole "forward" containing chromophore was synthesized. The first order hyperpolarizabilities of these compounds were examined using hyper-Raleigh scattering (HRS) technique. Results obtained at 1.3mum and 880nm revealed that the regiochemical orientation of the thiazole has a marked effect on the hyperpolarizability. Thiazole "forward" showed a 20% improvement in hyperpolarizability relative to chloroform compared to that of thiazole "backward." An additional examination of two of these compounds with respect to their bulk nonlinear optical activity showed that the novel thiazole "forward" containing chromophore possessed an inherit instability in its structure compared to that of its thiophene analogue. The degradation of the thiazole "forward" chromophore occurred through a [4+2] cycloaddition reaction with DMSO. Recommendations to improve the stability of future thiazole "forward" chromophores were discussed. Overall, the first order hyperpolarizability of thiazole containing chromophores can be tailored, but are not stronger than their thiophene analogue. en_US
dc.format.extent vii, 131 p. en_US
dc.language.iso en_US en_US
dc.rights.uri en_US
dc.subject.other Theses--Chemistry en_US
dc.title Systematic study of thiazole incorporated NLO gradient bridge chromophores en_US
dc.type Thesis en_US


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