Now showing items 1-5 of 5
Discovery based yeast metabolomic analysis using comprehensive two-dimensional gas chromatography with time-of-flight mass spectrometry and chemometrics
Comprehensive two-dimensional (2D) separations are highly beneficial in the characterization of complex samples. The research presented in this dissertation involves the analysis of the small polar molecules comprising the yeast metabolome using commercially available GCxGC-TOFMS instrumentation. The studies described herein ...
Molecular and nanoscale engineering for enhanced order in organic electro-optic materials
Intermolecular interactions play a critical role in organic electro-optic materials. Through careful molecular design and optimization, we explore the effect of these interactions on molecular properties, nanoscale acentric order, and ultimately macroscopic electro-optic activity. Discotic chromophores, designed to reduce ...
Dyeing crystals: 19th century phenomenology to 21st century technology
The linear dichroism of organic light-absorbing molecules (dyes) contained within varied solid matrices are analyzed. Hosts of increasing disorder from single crystals, to organized polycrystalline formations, to polymers are examined. Organic chromophores contained within single crystal hosts serve as optical reporters of ...
Electron spin dynamics in quantum dots, and the roles of charge transfer excited states in diluted magnetic semiconductors
In this dissertation, photoelectrochemical measurements have been used in combination with absorption and magnetic circular dichroism spectroscopic measurements to investigate the electronic structural properties of nanocrystalline Co2+:ZnO and Mn2+:ZnO diluted magnetic semiconductors that give rise to macroscopic charge ...
Biomimetic Modeling of Superoxide Reductase
(University of Washington, 2007-07-17)
Dioxygen is a thermnodynamically superior oxidam. with the ability to be reduced to water by a four-electron reduction. During this process, toxic reactive oxygen sPeciCis (ROS) are also generated. Nature uses metalloenzymes to combat this form of oxidative stress. Of particular interest to us is superoxide reductase (SOR). ...