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Small Molecule Activation Studies Involving Thiolate-Ligated Manganese(II) Complexes and Biologically-Relevant Oxidants
This dissertation focuses upon the synthesis, characterization, and reactivity of thiolate-ligated manganese complexes. Chapter 1 provides a brief introduction to the importance of manganese ions in biology, as well as the unique properties promoted by thiolate ligands. Chapter 2 discusses the synthesis and characterization ...