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Mechanistic studies of the oxidations of hydrocarbons by manganese and ruthenium transition metal complexes
The oxidation of hydrocarbon C-H and O-H bonds can occur by a variety of mechanisms. These include stepwise processes such as initial electron or proton transfer, or concerted mechanisms such as hydride transfer or hydrogen-atom abstraction. Hydrocarbons containing weak C-H and O-H bonds are oxidized by Mn(hfacac)3 (hfacac = ...