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Platinum(II) olefin hydroarylation catalysts: tuning selectivity for the anti-Markovnikov product Tandem catalytic ester hydrogenation and deoxygenation of polyethylene terephthalate
PtII complexes bearing unsymmetrical pyridyl-pyrrolide ligands are shown to catalyze the hydroarylation of unactivated alkenes with high selectivity for the anti-Markovnikov product. Substitution on the pyrrolide portion of the ligand allows for effective tuning of the selectivity to anti-Markovnikov alkylarene products while ...