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Adsorption and Thin-Film Adhesion on Single-Crystalline Surfaces: Enthalpies, Entropies, and Kinetic Prefactors for Surface Reactions
(2014-02-24)
Chemical bonding at solid surfaces and interfaces is influential in a wide range of important technological applications including catalysis, fuel cells, batteries, chemical sensors, and device fabrication for microelectronics, computers, solar cells, and all variety of coatings. Adsorption and adhesion energetics are key ...
Probing Local Heterogeneity in the Optoelectronic Properties of Organic-Inorganic Perovskites Using Fluorescence Microscopy
Unregulated emission of carbon dioxide and greenhouse gases into our atmosphere has led to an increase in the average global surface air temperature, to a disruption of weather patterns, and to the acidification of oceans all of which threaten the continued prosperity of our race and our planet. The transition to renewable ...
New Tools for Studying Nanoscale Electrochemical Phenomena
This dissertation focuses primarily on the fabrication of micro and nanoscale electrochemical structures such as electrodes, electrode arrays, and nanopores. It also discusses the use of these tools in studying nanoscale electrochemical processes such as geometric considerations in redox molecule diffusion to nanoscale ...