Myers-Inspired Selenium-Mediated Isomerization: An Efficient Generation of Contra-Thermodynamic Allenes and Alkenes with the Potential for Reductive Deamination of Primary Amines and Metal-Free Hydrogenation of Dienes

dc.contributor.advisor	Michael, Forrest E
dc.contributor.author	Landing, Samuel Dane
dc.date.accessioned	2023-09-27T17:18:47Z
dc.date.available	2023-09-27T17:18:47Z
dc.date.issued	2023-09-27
dc.date.submitted	2023
dc.description	Thesis (Master's)--University of Washington, 2023
dc.description.abstract	Novel methods of catalytic metal-free isomerization reactions are scarce. By combining precedents in reductive defunctionalization reactions, coupled with previous advances in selenium-catalyzed C-N bond forming reactions, we have developed a contemporary but efficient manner of reaching contra-thermodynamic isomers of alkenes and alkynes. These isomerizations follow a well envisioned mechanistic path that may lead to further development in reductive deamination reactions, such as the reduction of primary amines such as anilines, and diamines to monoenes.
dc.embargo.terms	Open Access
dc.format.mimetype	application/pdf
dc.identifier.other	Landing_washington_0250O_25861.pdf
dc.identifier.uri	http://hdl.handle.net/1773/50734
dc.language.iso	en_US
dc.rights	none
dc.subject	contra-thermodynamic
dc.subject	isomerization
dc.subject	meyers'
dc.subject	olefin
dc.subject	selenium
dc.subject	Organic chemistry
dc.subject.other	Chemistry
dc.title	Myers-Inspired Selenium-Mediated Isomerization: An Efficient Generation of Contra-Thermodynamic Allenes and Alkenes with the Potential for Reductive Deamination of Primary Amines and Metal-Free Hydrogenation of Dienes
dc.type	Thesis

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